11/30/2023 0 Comments Melt chromium chloride crystals![]() ![]() Hydrogen bonds link the cation and anions. The hexahydrate consists of octahedral 3+ cation centers and chloride anions ( Cl −) as counterions. The melt conducts electricity poorly, unlike more ionic halides such as sodium chloride.Īluminium chloride monomer belongs to the point group D 3h in its monomeric form and D 2h in its dimeric form. At higher temperatures, the Al 2Cl 6 dimers dissociate into trigonal planar AlCl 3 monomer, which is structurally analogous to BF 3. Al 2Cl 6 dimers are also found in the vapour phase. ![]() This change in structure is related to the lower density of the liquid phase (1.78 g/cm 3) versus solid aluminium trichloride (2.48 g/cm 3). When aluminium trichloride is in its melted state, it exists as the dimer Al 2Cl 6, with tetracoordinate aluminium. Yttrium(III) chloride adopts the same structure, as do a range of other compounds. In this framework, the Al centres exhibit octahedral coordination geometry. Solid AlCl 3 has a sheet-like layered structure with cubic close-packed chloride ions. It is an example of an inorganic compound that reversibly changes from a polymer to a monomer at mild temperature.ĪlCl 3 adopts three structures, depending on the temperature and the state (solid, liquid, gas). The compound is often cited as a Lewis acid. It is mainly produced and consumed in the production of aluminium metal, but large amounts are also used in other areas of the chemical industry. The anhydrous form is important commercially. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour. It forms a hexahydrate with the formula Cl 3, containing six water molecules of hydration. Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl 3. ![]()
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![]() ![]() If you are stuck, just email us at we’ll get back to you asap. But it is so easy to use, we’re confident you’ll be just fine. The photo’s will automatically rotate to fill the screen beautifully. The design is sleek with a modern-meets-classic style. This digital photo frame measures 16 x 24 inches (40 x 61 cm), giving you an impressive display area. ![]() It’s a large wall-mounted frame that resembles a gallery-style picture frame. You can use the photo frame in either an upright or horizontal position. The Meural Canvas II is a digital photo frame for people proud of their photography. If you want to hide a photo, two simple touches on the touch screen will hide it. Only those that you allow will be able to send you photos. 12GB available for Photo and video storage. Thousands.! It has more storage space than you will ever need. It’s a free download on the Apple and Google App stores. Your family or friends will need to install the free ‘FRAMEO App’ on their phone. Pretty much any smart phone is supported (iPhones, Android, Samsung etc.). The best digital picture photo frames from Aura, Nixplay, Pix-Star and Google Nest with features like motion sensor, remote sharing, Wi-Fi access, app-compatibility, email, touchscreen, and more. What type of mobile phone is required to send photos? Only those sending you photos, will need a mobile phone. You don’t need a computer or mobile phone at all. Set up is done in a few minutes and you don’t need to do anything to receive and enjoy photos from loved ones.ĭo I need to have a mobile phone or computer? Grandparents Wooden Picture Frame - Only The Best Parents Get Promoted to Grandparents (Holds 5 x 7 Inch Photo) (9 x 11 Inch Overall Size) 84. There are no ongoing subscriptions or set up costs. It's super easy to use, in-fact, once set up (which is also super easy), you don’t need to do anything, just sit back and enjoy seeing new photos and videos as they appear in the slide show. ![]() And a t night, the photo frame will automatically switch off into sleep mode and turn itself on again in the morning. We use cookies to help give you the best experience on our site and to allow us and third parties to customise the marketing content you see across websites and. Photos automatically appear in a slide show or you can scroll through them at your own pace using the built-in touch screen. I t connects to the internet (using WiFi), so your friends and family can send precious moments (photos & videos) directly from their mobile phone to your beautiful connected digital photo frame.Ī personal message/caption can also be sent and is displayed with each photo. ‘ The Connected Photo Frame’ allows you to see all the latest family photos right where you want to see them, around your house. So choose wisely as per you want.These days, most photos are taken on our mobile phones and only shared on social media, but now there is a simple way to enjoy those precious memories without having to check facebook or social media. So, these were the ultimate picks from my side, that you can consider buying all the digital photo frames are quite different in terms of features & quality. Wrapping Up: Best Digital Photo Frames For Grandparents Power Source and Stand: Choose frames with a long-lasting battery or reliable power source and a sturdy stand for easy placement on tabletops or shelves.īy considering these factors, you can find the best digital photo frame for grandparents that brings joy to their hearts as they relive precious memories captured in vibrant digital displays.Remote Photo Management: Check if the frame has a mobile app or web platform that allows family members to remotely send photos to the frame.They also offer great offline functionality so that you donât. Top digital frames like the Pix-Star are easy to use, immersive, and can receive photos & other media from anywhere in the world in just a couple of moments. A digital picture frame is an excellent gift for grandparents. Wireless Connectivity: Consider frames with Wi-Fi or Bluetooth connectivity for easy photo sharing from smartphones and computers. Is A Digital Picture Frame The Best Gift For Grandparents.Slideshow and Transition Options: Ensure the frame offers various slideshow and transition options to customize the viewing experience.Storage Capacity: Look for frames with sufficient internal memory or the option to add external storage to hold a large number of photos.Ease of Use: Opt for a frame with a user-friendly interface and simple controls, allowing grandparents to easily navigate through their photos.Size and Display Quality: Choose a frame with a screen size that is easily viewable and has a high-resolution display for clear and vibrant photos.When looking for the best digital photo frames for grandparents, consider the following factors to bring their cherished memories to life: What To Look Before Buying Best Digital Photo Frames For Grandparents ? ![]() ![]() Unlike iTunes, YouTube does not have any portable media players. This is so much unlike iTunes where the format is in Mp3 format, meaning that the files consume lesser disk space. The files available on YouTube are primarily very large given that the files are in a video format. The quality provided is way more superior to that provided by YouTube for both its video and audio segments. ![]() ITunes makes up for the fact that its services are provided at a fee by making sure that audio and video quality is very high. Other than both platforms being a major source of entertainment for individuals across the globe, they compare differently on several metrics as outlined below. YouTube and iTunes compare a lot in very many ways. Tips: Why Convert YouTube Videos to iTunes Start converting YouTube to iTunesĬlick the "OK" button to start YouTube video to iTunes conversion, this FLV to iTunes Video Converter for Mac will get the rest done. If you want to upload the output files to your iPod, iPhone or iPad, you can select the presets offered. Select an output format from the pop-up format window. In the "Convert" tab, click the "+" icon to select your local videos from your Mac or PC computer. Import YouTube videos to the iTunes converter Steps to Convert YouTube Videos to iTunes You're also able to download video with iTube HD Video Downloader. It offers you ultra-fast conversion speed, loss-less video quality, extremely easy conversion steps. To convert YouTube to iTunes, this professional yet easy-to-use YouTube Video Downloader for Mac gives you a hassle free experience. you have to convert YouTube video to iTunes compatible formats like MOV, MP4 or M4V, if you wanna manage these files in iTunes. You might have noticed that the format of your YouTube files is FLV which is not recognized by iTunes, i.e. If you already have download YouTube videos to your Mac (High Sierra, Sierra included). Video Tutorial to Convert YouTube to iTunes Now you will have your YouTube videos in iTunes library. Lastly, click "OK" to start the conversion. Then check the option of "Export the output video/audio file(s) to iTunes". If you want to download and convert YouTube audio format like MP3 for iTunes, you should also import the video to "Convert" tab at first, then click the "Convert" icon and open "Audio" tab to select MP3 as the output format. And then check "Export the output video/audio file(s) to iTunes" option and start the conversion. To do so, click the "Convert" button in "Convert" tab and select iTunes compatible format, such as MPEG-4, AAC,AIFF, MP3, WAV, or M4A, as the output format. As we all know, most YouTube videos are in FLV format, so if you want to import YouTube to iTunes, you must convert YouTube to iTunes supported format. ![]() Once you finish YouTube download, you can go to view the videos and click "Add to Convert List" icon in the "Downloaded" tab to import your video to "Convert" tab. Convert YouTube to iTunes compatible formats Click the button and let the YouTube download wizard to do the thing for you. ![]() Go to YouTube, a "Download" button will show up at the top left corner of the video when it is detected on the webpage. Transfer downloaded YouTube video or music files to mobile devices like iPhone, iPad, Samsung or other Android devices.ĭownload and Convert YouTube to iTunes in Stepsĭownload and install this YouTube converter to iTunes. Support to download videos from YouTube, Vimeo, Dailymotion, Myspace, Metacafe, and 10,000+ in one click or just with the video URL.Ĭonvert downloaded YouTube videos or music videos to MP3 and support directly export the downloaded files to iTunes Library. YouTube to MP3 download mode to get music or audio from YouTube to iTunes. Download YouTube music to iTunes directly or extract audio for iTunes. ![]() 11/30/2023 0 Comments Dauntless heartseekers![]() ![]() The Spawn of Slaanesh are unbreakable monstrous infantry. One or two of these Marauders can certainly help defend your flanks, but it is better to just seek supremacy with your cavalry force. Your Hellstriders of Slaanesh are an all-around better option to defend against enemy cavalry or large units. Mythmaker Sivir (+ Prestige edition of this skin) Lunar God Qiyana. The following champions will be getting new skins: Mythmaker Irelia (Legendary) Mythmaker Galio. ![]() These Marauders with spears are not very cost-effective. This years event introduces new Mythmaker and Lunar Gods skins. Just do not expect them to win a fight against any other flying units. Then again, this is the only flying unit in the roster of Slaanesh, so if you want the flexibility of that in siege battles, Chaos Furies can remain somewhat useful. The Chaos Furies can be useful for Slaanesh in the early game, but when you can field (Heart)Seekers, there is not much reason to keep the Chaos Furies in your army. Due to the lack of units with high armor, your frontline will be bolstered a lot by two or three Soul Grinders. Typically, the Soul Grinder covers a weakness in the roster of a faction, and for Slaanesh, this is no different. It also deals with high armor-piercing damage. ![]() Tthe Soul Grinder of Slaanesh is a bit more melee-focused, with high armor. With their magical attacks with high armor-piercing damage and Devastating Flanker ability, they work well in conjunction with Marauders. These Fiends are a good monstrous infantry unit to bolster your army's frontline. Of course, you should not attack War Bear Riders with them, but against most low- and mid-tier cavalry, they will be quite effective. For their cost, you will be surprised by how effective they can be against enemy cavalry, thanks to their bonus versus large units. The Hellstriders of Slaanesh is a cheap cavalry unit with the same incredible speed as the (Heart)Seekers. Your Heartseekers will likely be among the top performers in your army in terms of getting the most kills. Play Dauntless for free on Playstation 4/5, Xbox Series XS, Xbox One, Nintendo Switch, and the Epic Games store with true cross-play and cross-progression. Their attacks are magical, deal poison damage, and have high armor-piercing. The Heartseekers is a Shock Cavalry unit and can be considered an upgrade from the Seekers. ![]() 11/30/2023 0 Comments Twilio pricing australia![]() If you need an account, you can sign up for a free Twilio account here!
11/30/2023 0 Comments Earth breeze cancel subscription![]() If you want to take a small step to protect the environment, these detergent strips may be for you.Īnd making the switch from liquid detergents to eco-friendly sheets like Earth Breeze will surely cut down on detergent overdosing, a common consumer mistake. Though probably unnecessary, the brand also offers a fragrance-free pack.Įarth Breeze Liquidless Eco Sheets are made for consumers who shudder at the thought of how much traditional detergent is dumped down washing machine drains and how many plastic bottles are piling up in our landfills. Earth Breeze is touted as being safe for sensitive skin. It could mean that Earth Breeze doesn’t leave residue on your clothes like other scented detergents can. You won’t necessarily get that with Earth Breeze it’s just not as strong. My white cottons looked dull, and despite the “fresh scent” claim on the packaging, the fragrance didn’t break through (even with two sheets) after the wash.Ī big appeal of laundry detergents is that fragrant after-wash “fresh” scent, which is psychologically tied to perceived cleanliness. (We use cool water in our lab tests.)Įven so, I found that the sheets lacked the fragrance and brightening power of liquid detergents, whose ingredients include surfactants, enzymes, chelators, oxidizers, color, and fragrance. The Earth Breeze sheets also purged odors and adequately cleaned my sweaty workout clothes and soiled towels, though the hot water I used probably helped. If you’re faced with tougher stains, though, you might want to supplement with stain remover sprays like the top-rated OxiClean MaxForce Spray. On the normal cycle, Earth Breeze Eco Sheets seemed to do a fair job of eliminating odors and sufficiently cleaning my colored shirts, removing olive oil, raspberry syrup, and soy sauce stains (hey, sushi and chopsticks can be tricky) without any pretreatment. ![]() I relied on an unscientific method: a skeptical eye, a keen nose, and a Frigidaire compact top-load washer. As CR laundry expert Rich Handel says, “In our lab tests on tough stains, liquid and pod detergents clearly outperform these sheets.”Įxpecting the worst, I tried out these eco sheets at home. ![]() The sheets removed dirt better, but their poor performance on tannin stains (coffee) and protein stains (blood) dragged down their Overall Score. Earth Breeze Eco Sheets earned only fair scores for removing body oils, salad dressing, and chocolate. In our strict labs, engineers use a colorimeter to analyze how well the laundry detergents we test clean tough stains on fabric swatches. Hold onto your hat-here’s what we concluded: We scrutinized Earth Breeze Eco Sheets in our scientific labs and at home. For every pack sold, the company says it donates 10 Earth Breeze loads to nonprofits, shelters, and charities. At press time, subscribing could earn you a 40 percent discount via the Earth Breeze website, and $1.60 per order on Amazon. Subscription option: Earth Breeze Eco Sheets are mostly available online, by the pack or by subscription. ![]() ![]() Carbon neutral: According to the company, carbon emissions generated by producing and shipping Earth Breeze are offset by native tree plantings, energy upgrades for low-income families, urban agriculture, landfill diversion, and environmental education.(That’s a half-sheet per medium load, one sheet per large load, and two sheets per heavily soiled load.) For front-loaders, tear the sheets into smaller pieces and insert them into the detergent dispenser. Just load your clothes and toss the appropriate size sheet directly on top. No mess: There’s no measuring, dripping, or overdosing.Added to the drum with your laundry, these low-sudsing sheets dissolve during the wash in cold, warm, or hot water. Strips come in a pamphlet-sized compostable paper pack, taking up little space in your laundry cabinet. Biodegradable: Earth Breeze Eco Sheets feature some tongue-twisting ingredients, like glycerol and primary alcohol ethoxylate, but their manufacturer says they’re still hypoallergenic, vegan, and free of parabens, phosphates, bleaches, and dyes. ![]() 11/30/2023 0 Comments Hanri goodnotes stickers![]() ![]() When you download digital stickers they’ll typically come in one of the following formats:ġ. Here’s how to use your stickers with the Elements Tool ! If you are using GoodNotes, there is a handy built in tool that makes using digital stickers even easier! The Elements Tool on GoodNotes, which allows you to save and reinsert images, handwriting and basically anything all across your notes, makes it a perfect tool to manage your stickers. Tip to use: To download these stickers, click into the video and check the description for a download link. Here are a couple FREE digital sticker picks from us to you. If you buy from the GoodNotes Shop, the stickers will automatically appear in app, ready for you to use! Top 6 FREE Digital Sticker Picks ![]() ![]() The shop includes a range of both functional and decorative stickers for you to choose from to best achieve your studying or journaling goals. If you’re using GoodNotes, you can also get more digital stickers in the in-app shop. Try searching for videos about digital planning and you'll find many include free downloads. YouTube is another surprising source for digital stickers, with many creators offering free downloads or sharing tutorials on how to create your own. You can find a wide range of themes and styles to suit your preferences 2. The online marketplace known for its handmade and unique items offers a variety of digital stickers packs created by talented artists. There are various creators and digital planning enthusiasts that regularly share free and premium digital stickers on different online platforms. Some examples of this include to-do lists, sticky notes, diagrams, charts, tables and more! Where To Get Digital Stickers These stickers include elements that mimic real paper items that you would typically write on top of. Some examples of this include headings, calligraphy, emojis, washi tape, fun borders and more!įunctional digital stickers are designed with practicality in mind. With an array of vibrant colors, expressive illustrations, and captivating designs, they bring personality and liveliness to your notes. There are two main types of digital stickers that you'll find:ĭecorative digital stickers focus on aesthetics and self-expression. The individual sticker can now be resized, cropped or moved around to fit your specific needs! Different Types of Digital Stickers Individually select the stickers you want to use then copy and paste the digital sticker on your notes. Import the file into your note-taking app. If your stickers are laid out as one page in a sticker book format … Simply import them into your note-taking app and they’re ready to go. If your stickers are saved as individual PNGs… ![]() Here is a simple how-to guide on using stickers with these formats. Individual digital planner stickers can take the form of PNG or PDF files or multiple stickers can also be compiled into a sticker book format. Read on for an overview of how to use digital stickers, where to find them, and discover 11 of our favorite digital sticker packs to download and use right away! How to Use Digital Stickers Whatever the reason, digital stickers have got your back! Stickers are not just for paper anymore! Are you taking digital notes and looking for ways to spruce up your digital planner or bullet journal? Or perhaps you just want to add a bit of joy to your lecture notes? ![]() 11/30/2023 0 Comments Freedom riders![]() ![]() Reluctantly, President Kennedy moves towards committing federal troops, but Governor Patterson sends in the Alabama National Guard to separate the mob. The mob begins to throw rocks causing the church windows to shatter, tear gas seeps through the windows, children are sent to the basement of the church while Black men draw hidden pistols and prepare to defend their families. Inside the church, the blacks sing hymns trying to become more powerful then the mob through song. The mob turns over a car and sets it on fire, the marshals try and protect the church from assault and fire bombs. ![]() Outside the church, a mob of more than 3,000 whites harass and taunt the blacks and the Federal marshals that were protecting the church. On the 21st of May, more than 1,200 black citizens gather in the Reverend Abernathy's 1st Baptist church to honor the Freedom Riders having Dr.King speak in their support. One of the riders, William Barbee, tells reporters (from his hospital bed) "As soon as we've recovered from this, we'll start again." Another rider, Zwerg says, "We are prepared to die." Jude's hospital treated the wounded riders no matter what color they were. The freedom riders were later blamed for the violence that occurred that day. One of the riders, John Lewis, was struck by a wooden crate to the head. Reporters are beaten and their cameras are smashed, this is why there are no pictures of the attack in Montgomery. When the Freedom Riders begin to step off the bus, hundreds of Klansman swarm the Riders and scream "Get the niggers!" The Klansman attack with baseball bats, broken bottles and lead pipes. But when the bus reaches Montgomery, the highway patrol disappears. Afraid of Klan ambush, the bus heads south towards Montgomery at 90 miles an hour, escorted by Alabama highway patrol cars. ![]() 11/30/2023 0 Comments Aquatico watch review![]() ![]() The best things about it: Build quality and looks.Who?s it for? Divers and desk diver alike.Make and model:? Aquatico Sea Star V2 Green.If you like what you see, go check them out at. This watch is selling for $299 USD which is not bad for a watch with a Seiko NH35 automatic movement, ceramic bezel, and 300m in water resistance. This watch doesn’t just look great on the wrist, it’s also more than capable of doing its job as a real dive watch. As you can see there is a lot of lume used in the watch and it looks great.Īll of the Aquatico watches I have reviewed have proven to be a great deal for the money. This provides a great green glow that last for quite a long time. To keep with the whole green theme, the lume us also done using vinatage green. Using the same vintage green, the Nato strap looks perfect on this watch. This watch doesn’t just come with the bracelet, it also comes with a very nice Nato strap. ![]() The bracelet is well made and has a very durable feel to it. The stainless steel bracelet on the Aquatico Sea Star is done in the same brushed finish as the case. For sure you can take this down on just about any recreational dive. Ókeypis heimsending, 14 daga auðveld skil og 12 mánaða ábyrg ð. Water resistance is a respectable 300m or approx 1000ft. Movement of the bezel is tight, but not too tight where it would be an issue under water. The coin edging on the bezel gives just the right amount of grip. The 120 click bezel has a ceramic insert which can take a good amount of abuse without scratching. For measurements, it comes in at 42mm in diameter, 50mm lug to lug, and 14.5mm thick. This watch is built from solid 316L stainless steel with a brushed finish. Protecting all of this is an inner AR-coated sapphire crystal. In the light, the green really pops, but when things get darker the color goes more to a grey. The face and bezel are done in a really cool looking vintage green. The hour and minute blade hands are large enough to be easily seen during any dive condition. This is a simple three-hander with no date. The dial on the Aquatico Sea Star is clean and simple, as a dive watch should be. The more time I spent with it the more I liked it. At first I wasn’t sure about the color but it quickly grew on me. This new Aquatico Sea Star V2 just came in the mail and it was green, Vintage green. I have done quite a few Aquatico watch reviews which you can see here. ![]() 11/30/2023 0 Comments Black forest cheesecake slice![]() ![]() Place in oven and fill roasting pan with hot water, one quarter of the way up the sides of springform pan (this is called a "water bath" and it will help prevent your cheesecake from cracking). Place springform pan inside a larger pan (a large roasting pan is good). Preheat oven to 300 degrees F/150 degrees C. Remove and let cool.Ĭombine sour cream, sweetened condensed milk and cream cheese in bowl of an electric mixer and beat on medium speed until well blended, then add sugar, cocoa, vanilla extract and eggs. Press crumb mixture into the bottom of prepared springform pan. Place crumbs in medium size mixing bowl and add the 1/4 cup sugar, melted butter and egg white. Place graham crackers in food processor and process until finely ground. Spray a 10-inch springform pan with nonstick cooking spray. If using a dark non-stick springform pan, set oven to 300 degrees F/150 degrees C). Preheat oven to 350 degrees F/180 degrees C. (1/4 stick/2 oz./28g) unsalted butter, meltedĢ (8 oz.) packages cream cheese, softened Kirsch is a clear cherry brandy that can be found at most large supermarkets in the liquor department or at most liquor stores.ġ 1/2 cups chocolate graham cracker crumbs (about 8 graham cracker squares)Ģ tbsp. This is also done with a traditional black forest cake. Kirsch is used in this recipe to sprinkle over the top of the cheesecake once it's baked. Black Forest Cherry Cheesecake in Diana's Recipe Book ![]() |
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